A self-assembled tetracopper triple-stranded helicate: Towards the controlled synthesis of finite one-dimensional magnetic chains

被引：50

作者：

Matthews, CJ

Onions, ST

Morata, G

Davis, LJ

Heath, SL

Price, DJ

机构：

[1] Nottingham Trent Univ, Dept Chem & Phys, Nottingham NG11 8NS, England

[2] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[3] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 27期

关键词：

copper; helical structures; magnetism; N ligands; self-assembly;

D O I：

10.1002/anie.200351634

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spiraling into control: A finite linear arrangement of four magnetically coupled copper(II) centers has been generated within a triple-stranded helical motif that was formed through a strict self-assembly process between a single octadentate ligand and CuII ions (see picture). This approach opens the way to constructing finite one-dimensional magnetic chains in a controlled manner.

引用

页码：3166 / 3169

页数：4

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