Benzoxazole-Based Heterometallic Dodecanuclear Complex [Dy4IIICu8II] with Single-Molecule-Magnet Behavior

被引：55

作者：

Iasco, Olga ^{[1
]}

Novitchi, Ghenadie ^{[1
,2
]}

Jeanneau, Erwann ^{[1
]}

Wernsdorfer, Wolfgang ^{[3
]}

Luneau, Dominique ^{[1
]}

机构：

[1] Univ Lyon 1, Lab Multimat & Interfaces, UMR 5615, F-69622 Villeurbanne, France

[2] Moldavian Acad Sci, Inst Chem, MD-2028 Kishinev, Moldova

[3] CNRS, Inst Neel, F-38042 Grenoble 9, France

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 16期

关键词：

TB; DY; LN; MAGNETIZATION; CLUSTERS; GD; HO; RELAXATION; ANISOTROPY; FAMILY;

D O I：

10.1021/ic201070n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three Cu-Ln (Ln = Dy, Gd, Y) dodecanuclear clusters assembled by a novel ligand of the benzoxazole type are reported. The dysprosium cluster exhibits a frequency dependence of the alternating-current susceptibility and hysteresis loop at low temperature, indicating single-molecule-magnet behavior.

引用

页码：7373 / 7375

页数：3

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