Combustor of ceramic Pt/alumina catalyst and its application for micro-thermoelectric hydrogen sensor

被引:31
作者
Choi, Y [1 ]
Tajima, K [1 ]
Shin, W [1 ]
Izu, N [1 ]
Matsubara, I [1 ]
Murayama, N [1 ]
机构
[1] Adv Mfg Res Inst, AIST, Moriyama Ku, Nagoya, Aichi 4638560, Japan
关键词
micro-thermoelectric hydrogen sensor; Pt/alumina catalyst; dispenser technique;
D O I
10.1016/j.apcata.2005.03.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A combustor of Pt/alumina catalyst was developed for the integration on a micro-thermoelectric hydrogen sensor (mu-THS) with a dispenser technique. The Pt/alumina catalyst was deposited on Si substrate and the hydrogen/air mixture gas was flowed to test the combustion performance. The temperature difference, developed by the heat generated from hydrogen oxidation on the catalyst, between the catalyst surface and the Si substrate showed its maximum at the Pt content of 40 wt.% in the catalyst. The effect of the catalyst size on the thermoelectric voltage (Delta V-s) of mu-THS was investigated. The catalyst (phi = 0.8 mm) smaller than the membrane developed the highest AV, because of its good thermal insulation. For the gas mixture of hydrogen/air, the mu-THS showed a wide range of hydrogen detection, 50 ppm-3%, with the Delta V-s of 0.03-31.74 mV, respectively, at room temperature. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:19 / 24
页数:6
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