Fine nanostructure analysis of single-wall carbon nanohorns by surface-enhanced Raman scattering

被引:23
作者
Fujimori, Toshihiko [1 ]
Urita, Koki [1 ]
Aoki, Yuusuke [1 ]
Kanoh, Hirofumi [1 ,2 ]
Ohba, Tomonori [1 ,2 ]
Yudasaka, Masako [3 ]
Iijima, Sumio [3 ,4 ]
Kaneko, Katsumi [1 ,2 ]
机构
[1] Chiba Univ, Grad Sch Sci & Technol, Chiba 2638522, Japan
[2] Chiba Univ, Fac Sci, Dept Chem, Chiba 2638522, Japan
[3] NEC Corp Ltd, Japan Sci & Technol Agcy, Tsukuba, Ibaraki 3058501, Japan
[4] Meijo Univ, Dept Phys, Nagoya, Aichi 4688502, Japan
关键词
D O I
10.1021/jp801416b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
Surface-enhanced Raman scattering (SERS) was applied to investigate the fine nanostructure of single-wall carbon nanohorns (SWCNHs) and partially oxidized SWCNHs of which Raman D bands are predominant. SERS of SWCNH samples was measured in vacuo by deposition of SWCNH particles on silver foil with evaporation of SWCNHs-dispersed solvent. New peaks were observed over the wavenumber range of 200 to 1700 cm(-1) in addition to peaks observed in normal Raman scattering. The new SERS peaks are tentatively assigned to the vibrational mode due to topological defects such as the pentagon and heptagon.
引用
收藏
页码:7552 / 7556
页数:5
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