Compression-rate dependence of the phase transition from hexagonal ice to ice II and/or ice III

被引：31

作者：

Bauer, Marion ^{[1
]}

Elsaesser, Michael S. ^{[2
]}

Winkel, Katrin ^{[1
]}

Mayer, Erwin ^{[1
]}

Loerting, Thomas ^{[2
]}

机构：

[1] Univ Innsbruck, Inst Gen Inorgan & Theoret Chem, A-6020 Innsbruck, Austria

[2] Univ Innsbruck, Inst Phys Chem, A-6020 Innsbruck, Austria

来源：

PHYSICAL REVIEW B | 2008年 / 77卷 / 22期

关键词：

D O I：

10.1103/PhysRevB.77.220105

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We study the density-driven phase transition from hexagonal ice in the temperature range of 170-230 K up to pressures of 0.65 GPa using a piston-cylinder apparatus. Pure ice II, pure ice III, or mixtures of ice II and ice III are identified as products when the compression-rate is varied from 0.001-4 GPa/min. At low compression-rates and at high temperatures, formation of ice II is observed, which is in accordance with the phase diagram. However, at low temperatures and at higher compression rates, formation of metastable ice III is observed, which extends the known temperature range for possible formation of ice III. Metastable ice III rather than stable ice II crystals are produced by simple variation of the compression rate, which is an uncommon concept of producing metastable phases. We discuss some implications for our understanding of the interior of icy satellites such as Ganymede.

引用

页数：4

共 45 条

[1] Preferred crystallographic orientation in the ice I->II transformation and the flow of ice II [J].

Bennett, K ;

Wenk, HR ;

Durham, WB ;

Stern, LA ;

Kirby, SH .

PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1997, 76 (02) :413-435

[2] TRANSFORMATIONS OF ICE II, ICE III, AND ICE V AT ATMOSPHERIC PRESSURE [J].

BERTIE, JE ;

WHALLEY, E ;

CALVERT, LD .

JOURNAL OF CHEMICAL PHYSICS, 1963, 38 (04) :840-&

[3] Possible presence of high-pressure ice in cold subducting slabs [J].

Bina, CR ;

Navrotsky, A .

NATURE, 2000, 408 (6814) :844-847

[4]

Bridgman P. W., 1912, P AM ACAD ARTS SCI, V13, P439, DOI [DOI 10.2307/20022754, 10.2307/20022754]

[5] ICE-RICH MOONS AND THE PHYSICAL-PROPERTIES OF ICE [J].

CONSOLMAGNO, GJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (21) :4204-4208

[6] EVOLUTION OF ICY SATELLITE INTERIORS AND SURFACES [J].

CONSOLMAGNO, GJ ;

LEWIS, JS .

ICARUS, 1978, 34 (02) :280-293

[7] Pressure-induced transformation plasticity of H2O ice [J].

Dunand, DC ;

Schuh, C ;

Goldsby, DL .

PHYSICAL REVIEW LETTERS, 2001, 86 (04) :668-671

[8] Creep of water ices at planetary conditions: A compilation [J].

Durham, WB ;

Kirby, SH ;

Stern, LA .

JOURNAL OF GEOPHYSICAL RESEARCH-PLANETS, 1997, 102 (E7) :16293-16302

[9] WATER ICE PHASE-II, PHASE-III, AND PHASE-V - PLASTIC-DEFORMATION AND PHASE-RELATIONSHIPS [J].

DURHAM, WB ;

KIRBY, SH ;

HEARD, HC ;

STERN, LA ;

BORO, CO .

JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH AND PLANETS, 1988, 93 (B9) :10191-10208

[10] EXPERIMENTAL DEFORMATION OF POLYCRYSTALLINE H2O ICE AT HIGH-PRESSURE AND LOW-TEMPERATURE - PRELIMINARY-RESULTS [J].

DURHAM, WB ;

HEARD, HC ;

KIRBY, SH .

JOURNAL OF GEOPHYSICAL RESEARCH, 1983, 88 :B377-B392

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