Synthesis, characterization and fabrication of solar cells making use of [Ru(dcbpy)(tptz)X]X (where X = Cl-, SCN-, CN-) complexes

被引：10

作者：

Anandan, S ^{[1
]}

Latha, S ^{[1
]}

Murugesan, S ^{[1
]}

Madhavan, J ^{[1
]}

Muthuraaman, B ^{[1
]}

Maruthamuthu, P ^{[1
]}

机构：

[1] Univ Madras, Dept Energy, Madras 600025, Tamil Nadu, India

来源：

SOLAR ENERGY | 2005年 / 79卷 / 05期

关键词：

Ru; triazine; semiconductor; conducting glasses; TiO2 solar cells;

D O I：

10.1016/j.solener.2005.01.006

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Dye-sensitized TiO2 solar cells were fabricated using tridentate ligand ruthenium(II) complexes, [Ru(dcbpy)(tptz)X]X (where dcbpy = 4,4'-dicarboxy-2,2'-bipyridine, tptz = 2,4,6-Tris(2-pyridyl)-s-triazine and X = Cl-, SCN-, CN-) attached to sol-gel processed TiO2 electrodes. The ligand tptz functions as spectator ligand and dcbpy functions as the anchoring ligand with sufficient visible light absorption. The synthesized complexes were characterized before using them in solar cells. The functioning of the solar cells fabricated using different conducting glasses was monitored and the current-voltage characteristics were measured. The efficiencies of different cells were calculated and compared. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：440 / 448

页数：9

共 62 条

[1]

Adamson A.W., 1982, PHYS CHEM SURFACES

[2] DESIGN OF ANTENNA-SENSITIZER POLYNUCLEAR COMPLEXES - SENSITIZATION OF TITANIUM-DIOXIDE WITH [RU(BPY)2(CN)2]2RU(BPY(COO)2)22- [J].

AMADELLI, R ;

ARGAZZI, R ;

BIGNOZZI, CA ;

SCANDOLA, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (20) :7099-7103

[3] Synthesis and characterization of naphthyridine and acridinedione ligands coordinated ruthenium(II) complexes and their applications in dye-sensitized solar cells [J].

Anandan, S ;

Madhavan, J ;

Maruthamuthu, P ;

Raghukumar, V ;

Ramakrishnan, VT .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2004, 81 (04) :419-428

[4]

ANANDAN S, 2000, P 13 INT C PHOT CONV

[5] Remote interfacial electron transfer from supramolecular sensitizers [J].

Argazzi, R ;

Bignozzi, CA ;

Heimer, TA ;

Meyer, GJ .

INORGANIC CHEMISTRY, 1997, 36 (01) :2-3

[6] LONG-LIVED PHOTOINDUCED CHARGE SEPARATION ACROSS NANOCRYSTALLINE TIO2 INTERFACES [J].

ARGAZZI, R ;

BIGNOZZI, CA ;

HEIMER, TA ;

CASTELLANO, FN ;

MEYER, GJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (47) :11815-11816

[7] A THIN-FILM SOLAR-CELL CONSISTING OF PHENOSAFRANIN IN A POLYMER MATRIX [J].

BHOWMIK, BB ;

JANA, AK .

ENERGY, 1988, 13 (10) :755-759

[8] FACTORS INFLUENCING EFFICIENCIES OF TIO2-SENSITIZED PHOTODEGRADATION .1. SUBSTITUTED BENZOIC-ACIDS - DISCREPANCIES WITH DARK-ADSORPTION PARAMETERS [J].

CUNNINGHAM, J ;

ALSAYYED, G .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (23) :3935-3941

[9] In situ infrared spectroscopic analysis of the adsorption of ruthenium(II) bipyridyl dicarboxylic acid photosensitisers to TiO2 in aqueous solutions [J].

Duffy, NW ;

Dobson, KD ;

Gordon, KC ;

Robinson, BH ;

McQuillan, AJ .

CHEMICAL PHYSICS LETTERS, 1997, 266 (5-6) :451-455

[10] DYNAMICS OF LIGHT-INDUCED WATER CLEAVAGE IN COLLOIDAL SYSTEMS [J].

DUONGHONG, D ;

BORGARELLO, E ;

GRATZEL, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (16) :4685-4690

← 1 2 3 4 5 6 7 →