Electrochromic and photoluminescence properties of vanadium bronze films formed by electrodeposition

被引：6

作者：

Kaneko, Y ^{[1
]}

Li, JT ^{[1
]}

Chen, L ^{[1
]}

机构：

[1] Yamamashi Univ, Fac Engn, Kofu, Yamanashi 4000016, Japan

来源：

DENKI KAGAKU | 1998年 / 66卷 / 12期

关键词：

vanadium; bronze film; electrochromism; photoluminescence spectrum;

D O I：

10.5796/kogyobutsurikagaku.66.1323

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The vanadium bronze film was synthesized onto the ITO electrode by periodic reverse potential electrolysis (PR). The obtained film was analyzed by x-ray diffraction and atomic force microscopy (AFM). Moreover, the electrochromic reaction of the vanadium bronze film as electrodeposited and the film annealed at 350 degrees C for 2 hours were investigated. Potential dependence of photoluminescence spectra of vanadium bronze film in propylene carbonate (PC) solution was discussed by measuring the in situ photoluminescence spectra. The luminescencemetry may be an effective method for characterization of electrochromic films.

引用

页码：1323 / 1328

页数：6

共 11 条

[1] ESTABLISHMENT OF AN OPTICAL SCALE FOR LEWIS BASICITY IN INORGANIC OXYACIDS, MOLTEN SALTS, AND GLASSES [J].

DUFFY, JA ;

INGRAM, MD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (24) :6448-&

[2] PREPARATION OF STRONTIUM DOPED BETA-LITHIUM VANADIUM BRONZES BY MOLTEN-SALT ELECTROLYSIS [J].

KANEKO, Y ;

OKAZAKI, T ;

KOJIMA, H .

DENKI KAGAKU, 1993, 61 (04) :410-414

[3] PHOSPHORESCENCEMETRY AND ACID-BASE REACTIONS OF VANADIUM-OXIDES IN MOLTEN BISULFATE, DIMETHYLSULFONE AND SOME SOLVENTS [J].

KANEKO, Y .

DENKI KAGAKU, 1994, 62 (06) :508-512

[4]

KANEKO Y, 1989, DENKI KAGAKU, V57, P1198

[5]

KANEKO Y, 1983, JIMIS, V3

[6]

Lampert C.M., 1990, LARGE AREA CHROMOGEN

[7]

MARFUNIN AS, 1979, PHYSICS MINERALS INO, P238

[8] SOL-GEL SYNTHESIS OF ELECTROCHROMIC FILMS [J].

NABAVI, M ;

DOEUFF, S ;

SANCHEZ, C ;

LIVAGE, J .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1989, 3 (1-2) :203-207

[9]

PASSERINI S, 1994, 1 INT M EL MIR VEN O, P44

[10] ELECTROCHEMICAL-BEHAVIOR OF SOME TRANSITION-METAL OXIDES IN MOLTEN DIMETHYLSULFONE AT 150-DEGREES-C [J].

PEREIRARAMOS, JP ;

MESSINA, R ;

PERICHON, J .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1986, 16 (03) :379-386

← 1 2 →