Stable deacon process for HCl oxidation over RuO2

被引：122

作者：

Crihan, Daniela ^{[1
]}

Knapp, Marcus ^{[1
]}

Zweidingey, Stefan ^{[1
]}

Lundgren, Edvin ^{[4
]}

Weststrate, Cornelis J. ^{[4
]}

Andersen, Jesper N. ^{[4
]}

Seitsonen, Ari P. ^{[2
,3
]}

Over, Herbert ^{[1
]}

机构：

[1] Univ Giessen, Inst Phys Chem, D-35392 Giessen, Germany

[2] CNRS, IMPC, F-75252 Paris, France

[3] Univ Paris 06, F-75252 Paris, France

[4] Lund Univ, Natl Synchrotron Radiat Res, S-22362 Lund, Sweden

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 11期

关键词：

deacon process; heterogeneous catalysis; oxide surfaces; ruthenium dioxide; surface chemistry;

D O I：

10.1002/anie.200705124

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Selective substitution: In the oxidation of HCl with oxygen to give Cl2 and water, RuO2(110) serves as a stable, active model catalyst for the Sumitomo process (see picture; Ru in red and blue). The stability of the catalyst is related to the selective replacement of undercoordinated bridging surface O atoms (Obr) by Cl atoms (Clbr). The chlorination of RuO2-(110) is self-limiting, in that chlorine incorporation terminates when all bridging O atoms are replaced. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2131 / 2134

页数：4

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