A cryptand/bisparaquat [3]pseudorotaxane by cooperative complexation

被引:137
作者
Huang, FH
Fronczek, FR
Gibson, HW [1 ]
机构
[1] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA
[2] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA
关键词
D O I
10.1021/ja0355877
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The formation of the first cryptand/bisparaquat [3]pseudorotaxane appears to be highly cooperative. The apparent value of K2 is 17 times that of K1. Copyright © 2003 American Chemical Society.
引用
收藏
页码:9272 / 9273
页数:2
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