Molecular porphyrin-fullerene architectures

被引:111
作者
Guldi, DM [1 ]
机构
[1] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA
关键词
D O I
10.1351/pac200375081069
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This article describes the utilization of porphyrin and fullerene architectures-yielding artificial light-harvesting antenna and reaction center mimics-to tune the electronic coupling element between electron donor and electron acceptor and ultimately to affect the total reorganization energy. Most importantly, the effects that these parameters have on the rate, yield, and lifetime of the energetic charge-separated states are discussed.
引用
收藏
页码:1069 / 1075
页数:7
相关论文
共 25 条
[1]  
[Anonymous], 2002, FULLERENES SYNTHESIS
[2]  
[Anonymous], 1993, The Photosynthetic Reaction Center
[3]  
Balzani V, 2001, ELECT TRANSFER CHEM, VI-V
[4]   Templated regioselective and stereoselective synthesis in fullerene chemistry [J].
Diederich, F ;
Kessinger, R .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (06) :537-545
[5]   Supramolecular fullerene chemistry [J].
Diederich, F ;
Gómez-López, M .
CHEMICAL SOCIETY REVIEWS, 1999, 28 (05) :263-277
[6]   A macrocyclic [60]fullerene-porphyrin dyad involving π-π stacking interactions [J].
Dietel, E ;
Hirsch, A ;
Eichhorn, E ;
Rieker, A ;
Hackbarth, S ;
Röder, B .
CHEMICAL COMMUNICATIONS, 1998, (18) :1981-1982
[7]   Charge-transfer in a π-stacked fullerene porphyrin dyad:: evidence for back electron transfer in the 'Marcus-inverted' region [J].
Guldi, DM ;
Luo, CP ;
Prato, M ;
Dietel, E ;
Hirsch, A .
CHEMICAL COMMUNICATIONS, 2000, (05) :373-374
[8]   Parallel (face-to-face) versus perpendicular (edge-to-face) alignment of electron donors and acceptors in fullerene porphyrin dyads: The importance of orientation in electron transfer [J].
Guldi, DM ;
Luo, CP ;
Prato, M ;
Troisi, A ;
Zerbetto, F ;
Scheloske, M ;
Dietel, E ;
Bauer, W ;
Hirsch, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (37) :9166-9167
[9]   Fullerene-porphyrin architectures; photosynthetic antenna and reaction center models [J].
Guldi, DM .
CHEMICAL SOCIETY REVIEWS, 2002, 31 (01) :22-36
[10]   Fullerenes: three dimensional electron acceptor materials [J].
Guldi, DM .
CHEMICAL COMMUNICATIONS, 2000, (05) :321-327