Slow advection and diffusion through low permeability inclusions

被引:39
作者
Guswa, AJ [1 ]
Freyberg, DL [1 ]
机构
[1] Stanford Univ, Dept Civil & Environm Engn, Stanford, CA 94305 USA
基金
美国国家科学基金会;
关键词
solute transport; mass transfer; advection; diffusion; lenses;
D O I
10.1016/S0169-7722(00)00136-4
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Heterogeneous porous media with low permeability lenses can produce contaminant plumes with extended tails, Highly asymmetric breakthrough curves cannot be described well by an advection-dispersion equation (ADE) with a uniform velocity and dispersion coefficient. The character of such a solute plume depends on many factors, including plume size, the geometry and arrangement of the low permeability inclusions, and the transport through such regions. We develop an inclusion Peclet number that effectively characterizes the relative importance of advection and diffusion for transport within a low permeability lens. This inclusion Peclet number is a function of the far-field velocity, the effective diffusion coefficient, the length scale of the inclusion, and the ratio of the permeability of the lens to that of the surrounding matrix. We investigate the effects of a single, elliptical inclusion on the arrival of a solute at a downgradient control plane with numerical pal-tide tracking. Effects specific to advection or diffusion dominance within the inclusion are subtle: diffusion gives rise to more distributed tailing whereas advection produces behavior that is more abrupt. These slight differences are nor enough to allow one to determine the dominant process within the inclusion by observing the first three temporal moments alone. The time scale for the dominant transport process within the inclusion is the primary factor affecting the contaminant tailing. For high inclusion Peclet numbers (when advection dominates), the characteristic time varies with the permeability contrast, the far-field velocity, and the size and geometry of the inclusion. For low inclusion Peclet numbers (when diffusion dominates), the characteristic time varies with the size of the inclusion and the effective diffusion coefficient. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:205 / 232
页数:28
相关论文
共 46 条
[1]   FIELD-STUDY OF DISPERSION IN A HETEROGENEOUS AQUIFER .2. SPATIAL MOMENTS ANALYSIS [J].
ADAMS, EE ;
GELHAR, LW .
WATER RESOURCES RESEARCH, 1992, 28 (12) :3293-3307
[2]  
[Anonymous], 1989, FLOW TRANSPORT POROU, DOI DOI 10.1007/978-3-642-75015-1
[3]   Adsorption kinetics of toluene on soil agglomerates: Soil as a biporous sorbent [J].
Arocha, MA ;
Jackman, AP ;
McCoy, BJ .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1996, 30 (05) :1500-1507
[4]   Nonequilibrium solute transport parameters and their physical significance: Numerical and experimental results [J].
Bajracharya, K ;
Barry, DA .
JOURNAL OF CONTAMINANT HYDROLOGY, 1997, 24 (3-4) :185-204
[5]   LONG-TERM SORPTION OF HALOGENATED ORGANIC-CHEMICALS BY AQUIFER MATERIAL .2. INTRAPARTICLE DIFFUSION [J].
BALL, WP ;
ROBERTS, PV .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1991, 25 (07) :1237-1249
[6]   FIELD-STUDY OF DISPERSION IN A HETEROGENEOUS AQUIFER .1. OVERVIEW AND SITE DESCRIPTION [J].
BOGGS, JM ;
YOUNG, SC ;
BEARD, LM ;
GELHAR, LW ;
REHFELDT, KR ;
ADAMS, EE .
WATER RESOURCES RESEARCH, 1992, 28 (12) :3281-3291
[7]   Using flow interruption to identify factors causing nonideal contaminant transport [J].
Brusseau, ML ;
Hu, QH ;
Srivastava, R .
JOURNAL OF CONTAMINANT HYDROLOGY, 1997, 24 (3-4) :205-219
[8]   DEAD-END PORE VOLUME AND DISPERSION IN POROUS MEDIA [J].
COATS, KH ;
SMITH, BD .
SOCIETY OF PETROLEUM ENGINEERS JOURNAL, 1964, 4 (01) :73-84
[9]  
Crank J, 1979, MATH DIFFUSION
[10]   Effects of grain-scale mass transfer on the transport of volatile organics through sediments .1. Model development [J].
Cunningham, JA ;
Werth, CJ ;
Reinhard, M ;
Roberts, PV .
WATER RESOURCES RESEARCH, 1997, 33 (12) :2713-2726