A rapid screening, 'combinatorial-type' survey of the metalloligand chemistry of Pt2(PPh3)4(μ-S)2 using electrospray mass spectrometry

被引：49

作者：

Fong, SWA

Vittal, JJ

Henderson, W

Hor, TSA

Oliver, AG

Rickard, CEF

机构：

[1] Univ Waikato, Dept Chem, Hamilton, New Zealand

[2] Natl Univ Singapore, Fac Sci, Dept Chem, Singapore 117543, Singapore

[3] Univ Auckland, Dept Chem, Auckland, New Zealand

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 05期

关键词：

D O I：

10.1039/b009616b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrospray mass spectrometry is a rapid and powerful technique for a combinatorial-like survey of the chemistry of the metalloligand Pt-2(PPh3)(4)(mu -S)(2), leading to the successful isolation and crystallographic characterisation of the novel protonated species Pt-2(PPh3)(4)(mu -S)(mu -SH) together with a range of metallated derivatives.

引用

收藏

页码：421 / 422

页数：2

相关论文

共 26 条

[1] Gold complexes with thiosemicarbazones:: reactions of bi- and tridentate thiosemicarbazones with dichloro[2-(dimethylaminomethyl)phenyl-C1,N]gold(III), [Au(damp-C1,N)Cl2] [J].

Abram, U ;

Ortner, K ;

Gust, R ;

Sommer, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (05) :735-744

[2] HETEROMETALLIC PT-AU COMPLEXES WITH MU-3 S BRIDGING - SYNTHESES AND STRUCTURES OF PT2(PPH3)4(MU-SAUCL)2.2CH2CL2 AND PT2(PPH3)4-(MU-S)(MU-SAUPPH3)NO3.0.5H2O [J].

BOS, W ;

BOUR, JJ ;

SCHLEBOS, PPJ ;

HAGEMAN, P ;

BOSMAN, WP ;

SMITS, JMM ;

VANWIETMARSCHEN, JAC ;

BEURSKENS, PT .

INORGANICA CHIMICA ACTA, 1986, 119 (02) :141-148

[3] CHEMISTRY OF PLATINUM SULPHIDO-COMPLEXES .4. DIMERIC MU-ALKYLSULPHIDO-COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF "[PT2(MU-S)-(MU-SME)(PPH3)4]PF6.MEOH AND CIS-[PT2(MU-SME)2(NO2)2(PPH3)2] [J].

BRIANT, CE ;

GARDNER, CJ ;

HOR, TSA ;

HOWELLS, ND ;

MINGOS, DMP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (12) :2645-2651

[4] SYNTHESIS AND CHARACTERIZATION OF [AG2PT4(MU-S)4(PPH3)8](BF4)2.0.25CHCL3 [J].

BRIANT, CE ;

HOR, TSA ;

HOWELLS, ND ;

MINGOS, DMP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 256 (01) :C15-C18

[5] Extending knowledge on the nucleophilicity of the {Pt2S2} core:: Ph2PCH2CH2PPh2 as an alternative terminal ligand in [L2Pt(μ-S)2PtL2] metalloligands [J].

Capdevila, M ;

Carrasco, Y ;

Clegg, W ;

Coxall, RA ;

González-Duarte, P ;

Lledós, A ;

Ramírez, JA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (17) :3103-3113

[6] The first stable copper(II) complex containing four sulfide ligands:: synthesis and structural characterization of [Pt2(dppe)2(μ-S)2] and[Cu{Pt2(dppe)2(μ3-S)2}2]2+ [J].

Capdevila, M ;

Carrasco, Y ;

Clegg, W ;

Coxall, RA ;

González-Duarte, P ;

Lledós, A ;

Sola, J ;

Ujaque, G .

CHEMICAL COMMUNICATIONS, 1998, (05) :597-598

[7] Hinge distortion in platinum(II) dimers with a Pt2S2 ring. An ab initio molecular orbital study [J].

Capdevila, M ;

Clegg, W ;

GonzalezDuarte, P ;

Lledos, A .

INORGANIC CHEMISTRY, 1996, 35 (02) :490-497

[8] Replacement of the chloride ligand in [Au(C,N,N)Cl][PF6] cyclometallated complexes by C, N, O and S donor anionic ligands [J].

Cinellu, MA ;

Minghetti, G ;

Pinna, MV ;

Stoccoro, S ;

Zucca, A ;

Manassero, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (16) :2823-2831

[9] Electrospray mass spectrometry applied inorganic and organometallic chemistry [J].

Colton, R ;

DAgostino, A ;

Traeger, JC .

MASS SPECTROMETRY REVIEWS, 1995, 14 (02) :79-106

[10] Organogold(III) metallacyclic chemistry.: Part 3.: Self-assembly of the nonametallic gold(III)-silver(I)-sulfido aggregates [{LAu(μ-S)2AuL}3Ag3X2]+ (L = cycloaurated N,N-dimethylbenzylamine ligand; X = Cl, Br), by thiourea desulfurisation [J].

Dinger, MB ;

Henderson, W ;

Nicholson, BK ;

Robinson, WT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 560 (1-2) :169-181