Binary systems of C60 with positional isomers 1,2-and 1,3-C6H4Br2

被引：10

作者：

Avramenko, NV

Stukalin, EB

Korobov, MV ^{[1
]}

Neretin, IS

Slovokhotov, YL

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia

来源：

THERMOCHIMICA ACTA | 2001年 / 370卷 / 1-2期

基金：

俄罗斯基础研究基金会;

关键词：

DSC; fullerenes; solvates; solubility; isomers;

D O I：

10.1016/S0040-6031(00)00757-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermodynamic properties of binary systems of C-60 With 1,2- and 1,3-dibromobenzenes have been studied by means of differential scanning calorimetry (DSC). Solid solvates with the compositions C(60)3(1,2-C6HSBr2); C(60)2(1,3-C6H4Br2) and C(60)0.6(1,3-C6H4Br2) have been found. The solvates have been characterised by their enthalpies and temperatures of incongruent melting transition and in part by X-ray powder data. It has been shown that positional isomers 1,2- and 1,3- of the substituted benzenes formed two series of "typical' phase diagrams. Solubility behaviour of C-60 in positional isomers has been discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：21 / 28

页数：8

共 13 条

[1] Correlation and prediction of the solubility of Buckminster-fullerene in organic solvents; estimation of some physicochemical properties [J].