Absolute determination of reaction mechanisms by in situ measurements of reaction intermediates

被引：30

作者：

Oyama, ST ^{[1
]}

Li, W

机构：

[1] Virginia Polytech Inst & State Univ, Environm Catalysis & Mat Lab, Dept Chem Engn, Blacksburg, VA 24061 USA

[2] Virginia Polytech Inst & State Univ, Environm Catalysis & Mat Lab, Dept Chem, Blacksburg, VA 24061 USA

来源：

TOPICS IN CATALYSIS | 1999年 / 8卷 / 1-2期

关键词：

reaction mechanism; in situ Raman spectroscopy; reaction intermediate; ozone decomposition; manganese oxide;

D O I：

10.1023/A:1019148808462

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This paper presents a general methodology to determine reaction mechanisms using in situ measurement of concentration and reaction rate of intermediates. The criteria for testing the validity of a reaction sequence are discussed. An example is given for a heterogeneous catalytic reaction, the decomposition of ozone on manganese oxide.

引用

页码：75 / 80

页数：6

共 22 条

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