Characterization of low-spin ferric hydroperoxo complexes with N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)-1,2-diaminoethane

被引:18
作者
Duban, EA [1 ]
Bryliakov, KP [1 ]
Talsi, EP [1 ]
机构
[1] Russian Acad Sci, Siberian Branch, GK Boreskov Inst Catalysis, Novosibirsk 630090, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1070/MC2005v015n01ABEH001981
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydroperoxo intermediates formed by the interaction of [Fe-II(BPMEN)(MeCN)(2)](ClO4)(2) [BPMEN = NN'-dimethyI-NN'-bis(2-pyridylmethyl)-1,2-diaminoethaneI with H2O2 in a CH2Cl2-MeCN mixture were characterised using EPR spectroscopy.
引用
收藏
页码:12 / 14
页数:3
相关论文
共 15 条
  • [1] Evidence for the participation of a high-valent iron-oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst
    Chen, K
    Que, L
    [J]. CHEMICAL COMMUNICATIONS, 1999, (15) : 1375 - 1376
  • [2] Olefin cis-dihydroxylation versus epoxidation by non-heme iron catalysts:: Two faces of an FeIII-OOH coin
    Chen, K
    Costas, M
    Kim, JH
    Tipton, AK
    Que, L
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (12) : 3026 - 3035
  • [3] Biomimetic nonheme iron catalysts for alkane hydroxylation
    Costas, M
    Chen, K
    Que, L
    [J]. COORDINATION CHEMISTRY REVIEWS, 2000, 200 : 517 - 544
  • [4] Solid and solution state structures of mono- and di-nuclear iron(III) complexes of related hexadentate and pentadentate aminopyridyl ligands
    Duelund, L
    Hazell, R
    McKenzie, CJ
    Nielsen, LP
    Toftlund, H
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (02): : 152 - 156
  • [5] Functional models of non-heme diiron enzymes
    Fontecave, M
    Ménage, S
    Duboc-Toia, C
    [J]. COORDINATION CHEMISTRY REVIEWS, 1998, 178 : 1555 - 1572
  • [6] OXO-BRIDGED AND HYDROXO-BRIDGED DIIRON COMPLEXES - A CHEMICAL PERSPECTIVE ON A BIOLOGICAL UNIT
    KURTZ, DM
    [J]. CHEMICAL REVIEWS, 1990, 90 (04) : 585 - 606
  • [7] Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine
    Lobanova, MV
    Bryliakov, KP
    Duban, EA
    Taksum, EP
    [J]. MENDELEEV COMMUNICATIONS, 2003, (04) : 175 - 177
  • [8] Mekmouche Y, 2002, CHEM-EUR J, V8, P1196, DOI 10.1002/1521-3765(20020301)8:5<1196::AID-CHEM1196>3.0.CO
  • [9] 2-Z
  • [10] Synthesis, structure, and characterization of the new [L(OH)Fe(μ-O)Fe(OH2)L]3+ complex (L = N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)ethane-1,2-diamine).: Detection of an equilibrium with the protonated diamond form [LFe(μ-O)(μ-OH)FeL]3+ in acetonitrile
    Poussereau, S
    Blondin, G
    Cesario, M
    Guilhem, J
    Chottard, G
    Gonnet, F
    Girerd, JJ
    [J]. INORGANIC CHEMISTRY, 1998, 37 (13) : 3127 - 3132