Supramolecular aggregates as templates: Ordered mesoporous polymers and carbons

被引：410

作者：

Wan, Ying ^{[2
]}

Shi, Yifeng ^{[1
]}

Zhao, Dongyuan ^{[1
]}

机构：

[1] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Dept Chem, Shanghai 200433, Peoples R China

[2] Shanghai Normal Univ, Dept Chem, Shanghai 200234, Peoples R China

来源：

CHEMISTRY OF MATERIALS | 2008年 / 20卷 / 03期

关键词：

LYOTROPIC LIQUID-CRYSTALLINE; TUNABLE PORE-SIZE; BLOCK-COPOLYMER; MOLECULAR-SIEVES; FACILE SYNTHESIS; CURED TEMPLATES; POROUS CARBONS; SILICA; PYROLYSIS; ROUTE;

D O I：

10.1021/cm7024125

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Supramolecular aggregate's self-assembling approach has derived diverse mesostructured inorganic solids. Recent progresses involve ordered mesoporous carbonaceous frameworks. This review paper summarizes the synthesis of ordered mesoporous polymers and carbons based on the supramolecular aggregates as templates. Block copolymers are mainly introduced here. Both the aggregates of block copolymers themselves and the assembling with thermosetting resins have the abilities to organize ordered mesostructures. The understanding of the synthesis is on the formation of supramolecular arrangement of molecules, templating, cross-linking, removal of templates, and carbonization. In addition, the morphological control and the functionalization of ordered mesoporous carbonaceous materials are briefly summarized. The attractive mesoporous carbonaceous materials offer great opportunities in catalysis, water purification, electrodes, adsorbents, gas storage, aero-space, etc.

引用

页码：932 / 945

页数：14

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