Influence of activation temperature on adsorption characteristics of activated carbon fiber composites

被引:92
作者
Park, SJ [1 ]
Kim, KD [1 ]
机构
[1] Res Inst Chem Technol, Adv Mat Div, Taejon 306600, South Korea
关键词
activated carbon; carbon/carbon composite; BET surface area; adsorption properties; surface properties;
D O I
10.1016/S0008-6223(00)00305-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, the effect of activation temperature on adsorption properties of activated carbon fiber-reinforced phenolic resin matrix composites has been investigated. The composites were manufactured via a molding process with unwoven carbon fabrics and phenolic resin. The green body mold was heated at 125 degreesC to cure the phenolic resin and they were carbonized in an inert environment at 1000 degreesC for 2 h. They were then activated by CO2 gas at 700, 800, 900 and 1000 degreesC for 2 h, denoted as ACFC-700, ACFC-800, ACFC-900 and ACFC-1000. The specific surface area and the pore structure were evaluated from nitrogen adsorption data at 77 K, and the acid-base values on the surface were determined by titration methods. As a result, the activation temperatures had a major influence on adsorption characteristics and surface properties of the composites. (C) 2001 Published by Elsevier Science Ltd.
引用
收藏
页码:1741 / 1746
页数:6
相关论文
共 28 条
[1]   Comparison of equilibria and kinetics of high surface area activated carbon produced from different precursors and by different chemical treatments [J].
Ahmadpour, A ;
King, BA ;
Do, DD .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (04) :1329-1334
[2]  
[Anonymous], 1964, ANGEW CHEM-GER EDIT
[3]  
BANSAL RC, 1988, ACTIVE CARBON, P1
[4]   Surface functionality and porosity of activated carbons obtained from chemical activation of wood [J].
Benaddi, H ;
Bandosz, TJ ;
Jagiello, J ;
Schwarz, JA ;
Rouzaud, JN ;
Legras, D ;
Béguin, F .
CARBON, 2000, 38 (05) :669-674
[5]  
BLANCOLOPEZ MC, 2000, CARBON, V38, P1177
[6]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[7]  
DERBYSHIRE F, 1994, 8 ANN FOSS EN MAT C, P137
[8]   SCANNING-TUNNELING-MICROSCOPY STUDY OF ACTIVATED CARBON-FIBERS [J].
DONNET, JB ;
QIN, RY ;
PARK, SJ ;
RYU, SK ;
RHEE, BS .
JOURNAL OF MATERIALS SCIENCE, 1993, 28 (11) :2950-2954
[9]  
DONNET JB, 1990, CARBON FIBERS, V5, P259
[10]   The production of chemically-activated carbon [J].
Evans, MJB ;
Halliop, E ;
McDonald, JAF .
CARBON, 1999, 37 (02) :269-274