Magnetic anisotropy and ground state of the rare-earth ions in PrMnO3 and NdMnO3

被引:33
作者
Mukhin, AA
Ivanov, VY
Travkin, VD
Balbashov, AM
机构
[1] Russian Acad Sci, Inst Gen Phys, Moscow 117942, Russia
[2] Moscow Power Engn Inst, Moscow 105835, Russia
关键词
anisotropy-single ion; crystal field-excitation; exchange coupling; rare-earth-transition metal compounds;
D O I
10.1016/S0304-8853(00)00710-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A qualitatively different temperature behavior of the spontaneous weak ferromagnetic moment along the c-axis and anisotropy of magnetic susceptibility were observed in the PrMnO3 and NdMnO3 single crystals which is determined by anisotropic contributions of Pr3+ and Nd3+ ions. Electron transitions inside of the ground Pr3+ quasidoublet split by a crystal field and Nd3+ Kramers doublet split by exchange Mn-Nd field were revealed, respectively, at similar to 14.5 and similar to 14 cm(-1) in submillimeter transmission spectra and their g-tensor components and crystal field and exchange splitting were determined by fitting the overall experimental data. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1139 / 1141
页数:3
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