Biotransformation of caryophyllene oxide by Botrytis cinerea

被引：33

作者：

Duran, R ^{[1
]}

Corrales, E ^{[1
]}

Hernández-Galán, R ^{[1
]}

Collado, IG ^{[1
]}

机构：

[1] Univ Cadiz, Fac Ciencias, Dept Quim Organ, Cadiz 11510, Spain

来源：

JOURNAL OF NATURAL PRODUCTS | 1999年 / 62卷 / 01期

关键词：

D O I：

10.1021/np980104b

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Biotransformation of caryophyllene oxide (1) with B. cinerea afforded 15 products (2-16). Ten of these (3-5, 7, 9-11, and 14-16) are reported here for the first time. The main reaction paths involved stereoselective epoxidation at C-8/C-13 and hydroxylation at C-7. A rearranged compound was found, which was a cyclization product 16 possessing the caryolane skeleton.

引用

页码：41 / 44

页数：4

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