Synthesis and crystal structure of MIL-14:: a new layered fluoroaluminophosphate templated with tris(2-aminoethylamine):: Al2(HPO4)3F2•H2PO4•N4C6H21

被引：22

作者：

Simon, N ^{[1
]}

Loiseau, T ^{[1
]}

Férey, G ^{[1
]}

机构：

[1] Univ Versailles, Inst Lavoisier, CNRS, UMR 173, F-78035 Versailles, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1999年 / 9卷 / 02期

关键词：

D O I：

10.1039/a807303a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

MIL-14, formulated Al-2(HPO4)(3)F-2. H2PO4. N4C6H21, is a new layered fluoroaluminophosphate obtained by hydrothermal synthesis using tris(2-aminoethyl)amine as a template. It crystallizes in the monoclinic space group P2(1)/c with a = 13.154, b = 9.518, c = 17.889 Angstrom, beta = 106.165 degrees and Z = 4. Its structure consists of an alternation along [100] direction of inorganic layers interleaved by amine phosphates. The structural unit of the inorganic layer contains five polyhedra: two aluminium octahedra and three HPO4 tetrahedra. Strong hydrogen bonds ensured framework stability.

引用

页码：585 / 589

页数：5

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