The low temperature limit of the application of solid electrolyte potentiometry in heterogeneous catalysis

被引：14

作者：

Bruck, J

Lintz, HG

Valentin, G

机构：

[1] Univ Karlsruhe, Inst Chem Verfahrenstech, D-76128 Karlsruhe, Germany

[2] CNRS, Lab Sci Genie Chim, Grp ENSIC, F-54001 Nancy, France

来源：

SOLID STATE IONICS | 1998年 / 112卷 / 1-2期

关键词：

SEP; electrochemical cell; catalytic electrode; oxidic catalyst;

D O I：

10.1016/S0167-2738(98)00201-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solid Electrolyte Potentiometry is an electrochemical method to characterise the state of solid catalysts under working conditions. Its application is temperature limited due to polarization effects at the catalyst electrode. A new operational definition of this temperature limit is proposed which is based on the measurements of exchange current densities. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：75 / 78

页数：4

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