Influence of molecular order on charge carrier photogeneration in perylene derivative layer

被引:13
作者
Rybak, Andrzej [1 ]
Pisula, Wojciech [2 ]
Jung, Jaroslaw [1 ]
Ulanski, Jacek [1 ]
机构
[1] Tech Univ Lodz, Dept Mol Phys, PL-90924 Lodz, Poland
[2] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
关键词
photogeneration quantum yield; perylene derivative; X-ray scattering;
D O I
10.1016/j.tsf.2007.11.107
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
X-ray diffraction investigations show, that in the vacuum evaporated layers of 2,9-di(pent-3yl)-anthra[2,1,9-def:6,5,10-d'e'f]diisoquinoline-1,3,8,10-tetrone (PTCDI) the PTCDl molecules may have edge-on or face-on arrangement. For the samples with different molecular arrangement the dependences of the photogeneration quantum yield on electric field were determined by using the photoinduced surface potential decay technique. The obtained results were analysed using the Onsager's model of photogeneration. The clear influence of the molecular order on the photogeneration efficiency has been found. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:4201 / 4207
页数:7
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