About the influence of lattice vibrations on the diffusion of methane in a cation-free LTA zeolite

被引：61

作者：

Fritzsche, S

Wolfsberg, M

Haberlandt, R

Demontis, P

Suffritti, GB

Tilocca, A

机构：

[1] Univ Leipzig, Fak Phys & Geowissensch, D-04103 Leipzig, Germany

[2] Univ Calif Irvine, Inst Surface & Interface Sci, Irvine, CA 92697 USA

[3] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 296卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(98)01060-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of lattice vibrations on the diffusion of methane in st cation-free zeolite of structure Type LTA is examined. It is shown that contrary to earlier published results the self-diffusion coefficients obtained with flexible and with rigid lattices are practically the same. This finding is true over a wide range of temperatures and for different interaction parameters. The reason why earlier papers did not state this independence of D on the lattice vibrations is explained. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：253 / 258

页数：6

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