Crystal structure of an inclusion complex between dibenzo-24-crown-8 and tropylium tetrafluoroborate

被引：30

作者：

Lamsa, M ^{[1
]}

Suorsa, T ^{[1
]}

Pursiainen, J ^{[1
]}

Huuskonen, J ^{[1
]}

Rissanen, K ^{[1
]}

机构：

[1] UNIV JYVASKYLA,DEPT CHEM,FIN-40351 JYVASKYLA,FINLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 12期

关键词：

D O I：

10.1039/cc9960001443

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dibenzo-24-crown-8 encapsulates the non-disordered tropylium ion (C7H7+) with charge-transfer type pi-pi-interactions with average bond distances of 1.35 Angstrom and C-C-C angles of 129 degrees confirming a regular delocalised heptagon structure.

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页码：1443 / 1444

页数：2

相关论文

共 20 条

[1] TROPYLIUM ION-AROMATIC HYDROCARBON CHARGE-TRANSFER COMPLEXES [J].

FELDMAN, M ;

WINSTEIN, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (15) :3338-&

[2] SYNTHESIS, STRUCTURE, AND PHYSICAL-PROPERTIES OF 1,11-O-BENZENO[2]ORTHOCYCLO[2](1,2)TROPYLIOPHANE [J].

FUKAZAWA, Y ;

HARADA, S ;

INAI, A ;

OKAJIMA, T .

TETRAHEDRON LETTERS, 1993, 34 (52) :8493-8496

[3]

Gokel G.W, 1990, CROWN ETHERS CRYPTAN

[4] CRYSTAL AND MOLECULAR-STRUCTURE OF 6,7,9,10,12,13,20,21,23,24,26,27-DODECAHYDRODIBENZO[B,N][1,4,7,10,13,16,19,22]OCTAOXACYCLOTETRACOSIN (DIBENZO-24-CROWN-8) [J].

HANSON, IR ;

HUGHES, DL ;

TRUTER, MR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1976, (08) :972-976

[5] CRYSTAL-STRUCTURES OF COMPLEXES BETWEEN ALKALI-METAL SALTS AND CYCLIC POLYETHERS .9. COMPLEX FORMED BETWEEN DIBENZO-24-CROWN-8(6,7,9,10,12,13,20,21,23,24,26,27-DODECAHYDRODIBENZO[B,N][1,4,7,10,13,-16,19,22]OCTAOXACYCLOTETRACOSIN) AND 2 MOLECULES OF SODIUM O-NITROPHENOLATE [J].

HUGHES, DL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (22) :2374-2378

[6] STEREOMUTATION OF ENDO-2-PHENYL-ENDO-6-TROPYLIOBICYCLO[2.2.2]OCTANE TO THE EXO-6-TROPYLIO ISOMER - STERIC REPULSION BETWEEN THE PHENYL AND TROPYLIUM RINGS SHOWING INTRAMOLECULAR CHARGE-TRANSFER [J].

IKAI, K ;

TAKEUCHI, K ;

KOMATSU, K ;

TSUJI, R ;

KINOSHITA, T ;

OKAMOTO, K .

TETRAHEDRON LETTERS, 1989, 30 (01) :99-102

[7] THERMODYNAMIC AND KINETIC DATA FOR MACROCYCLE INTERACTION WITH CATIONS, ANIONS, AND NEUTRAL MOLECULES [J].

IZATT, RM ;

PAWLAK, K ;

BRADSHAW, JS ;

BRUENING, RL .

CHEMICAL REVIEWS, 1995, 95 (07) :2529-2586

[8]

KELLER E, 1992, SCHAKAL 92

[9]

KOMATSU K, 1979, TETRAHEDRON LETT, P4747

[10] PROBING ONIUM IONS AND CARBOCATIONS BY DESORPTION/IONIZATION MASS-SPECTROMETRY - CROSSING THE THRESHOLD BETWEEN FRAGILE SALTS AND GASEOUS INTACT CATIONS AND SUBSEQUENT GUEST-HOST AND CATION-MOLECULE CLUSTER CHEMISTRY [J].

LAALI, KK .

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1994, 7 (09) :465-478