Heterocycles as ligands .22. 2-chalcogenoimidazolines as ligands in pentacarbonylmetal complexes

被引：31

作者：

Kuhn, N ^{[1
]}

Fawzi, R ^{[1
]}

Kratz, T ^{[1
]}

Steimann, M ^{[1
]}

机构：

[1] UNIV DUISBURG GESAMTHSCH,FACHBEREICH CHEM 6,D-47048 DUISBURG,GERMANY

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1996年 / 108卷 / 1-4期

关键词：

imidazole; Group; 6; carbonyl; metal complexes; crystal structure;

D O I：

10.1080/10426509608029645

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chalcogenoimidazoline complexes NR-CMe-CMe-NR-C=X . M(CO)(5) (VIII-XI; R = Me, iso-Pr; X = S, Se, Te; M = Cr, Mo, W) are obtained from the metal hexacarbonyls (M = Cr, Mo, W) and the chalcogenoimidazolines IV-VIL. ln these complexes the chalcogeno ligands exhibit strong donor properties according to the sequence Te > Se > S which is demonstrated by n. m. r. and i. r. data. The X-ray structures of N(iso-Pr)-CMe-CMe-N(iso-Pr)-C=X . Cr(CO)(5)(X = S; Se; VIIIa, IXa) are reported.

引用

页码：107 / 119

页数：13

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