Synthesis of polycyclic Imines by palladium-catalyzed domino cyclization of Di- and trienyl ketone O-pentafluorobenzoyloximes

被引：48

作者：

Zaman, S ^{[1
]}

Kitamura, M ^{[1
]}

Narasaka, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2003年 / 76卷 / 05期

关键词：

D O I：

10.1246/bcsj.76.1055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various cyclic imines, such as spiro imines and a fused bicyclic imine, are synthesized from dienyl and trienyl ketone O-pentafluorobenzoyloximes by the domino amino-Heck reaction. Treatment of the oximes with a catalytic amount of Pd(PPh3)(4) and triethylamine gives polycyclic imines in high yields via alkylideneaminopalladium(II) intermediates generated in situ by the oxidative addition of the oximes to the Pd(0) complex.

引用

页码：1055 / 1062

页数：8

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