Supramolecular porphyrin-fullerene via 'two-point' binding strategy:: Axial-coordination and cation-crown ether complexation

被引：89

作者：

D'Souza, F

Chitta, R

Gadde, S

Zandler, ME

Sandanayaka, ASD

Araki, Y

Ito, O

机构：

[1] Wichita State Univ, Dept Chem, Wichita, KS 67260 USA

[2] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 10期

关键词：

D O I：

10.1039/b416736h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly stable porphyrin - fullerene conjugate with defined distance and orientation, was formed using a newly developed 'two-point' binding strategy involving axial-coordination and cation - crown ether complexation; photochemical studies performed in benzonitrile revealed efficient charge separation and slow charge-recombination in the supramolecular complex.

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收藏

页码：1279 / 1281

页数：3

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