Crystallographic and spectroscopic studies of a luminescent binuclear copper(I) complex containing mixed-ligands

被引：12

作者：

Sun, Y

Zhang, SW

Li, GL

Xie, YX

Zhao, D ^{[1
]}

机构：

[1] Henan Inst Chem, Zhengzhou 450002, Peoples R China

[2] Zhengzhou Light Ind Coll, Zhengzhou 450008, Peoples R China

[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2003年 / 28卷 / 07期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1023/A:1026021725435

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The luminescent binuclear copper(I) complex [Cu(dppm)(phen)](2)(NO3)(2) . 6H(2)O (dppm = Ph2PCH2PPh2, phen = 1,10-phenanthroline) has been prepared and characterized by physicochemical and spectroscopic methods. The complex is photoluminescent at room temperature. Its X-ray crystal structure shows that dppm coordinates as a bridging ligand, and phen as a bidentate ligand to the copper( I) atoms of the tetrahedral structure.

引用

页码：772 / 776

页数：5

共 13 条

[1] 2 BIS(DIPHENYLPHOSPHINOMETHANE) (DPPM) COMPLEXES OF QUADRUPLY BONDED DIMOLYBDENUM(II) - MO2(DPPM)2X4, X = CL, NCS [J].