Polyethylene/palygorskite nanocomposites with macromolecular comb structure via in situ polymerization

Polyethylene/palygorskite nanocomposites with "macromolecular comb" structure were prepared via in situ polymerization. The TiCl4 catalyst was first loaded on the surface of the nanoscale whiskers of palygorskite. Subsequently the ethylene was introduced into the reaction system, and the polyethylene molecular chain was generated directly at the surface of the palygorskite whiskers. As a result, a polyethylene molecular chain with "macromolecular comb" structure was generated. The product thus obtained was blended with regular polyethylene to make a polymer blend, which was characterized by transmission electron microscope (TEM). Finely dispersed palygorskite whiskers in polyethylene matrix were found, which resulted in the improvement of mechanical strength of the polymer blends. Compared with regular polyethylene, the impact strength and tensile strength of the polymer blend were improved by 63.5% and 21.3% respectively at 25degreesC, when the palygorskite content of the nanocomposite was 20 wt%. (C) 2003 Kluwer Academic Publishers.