Developments in Chiral Binaphthyl-Derived Bronsted/Lewis Acids and Hydrogen-Bond-Donor Organocatalysis

被引：159

作者：

Schenker, Sebastian ^{[1
]}

Zamfir, Alexandru ^{[1
]}

Freund, Matthias ^{[1
]}

Tsogoeva, Svetlana B. ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, Chair Organ Chem 1, D-91054 Erlangen, Germany

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 12期

关键词：

Organocatalysis; Bronsted acids; Lewis acids; Hydrogen bonds; Binaphthyl derivatives; BAYLIS-HILLMAN REACTION; LEWIS-BASE ACTIVATION; SILYL KETENE ACETALS; N-BOC IMINES; DICARBOXYLIC-ACID; ENANTIOSELECTIVE ADDITION; ASYMMETRIC ALLYLBORATION; CATALYSIS; MECHANISM; DESIGN;

D O I：

10.1002/ejoc.201001538

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In recent years, binaphthyl compounds have found frequent applications in the design of various asymmetric organocatalysts, because binaphthyl structures are an attractive platform for organocatalyst development, particularly in light of their axial chirality characteristic. In this review, we discuss recent achievements in developing enantioselective transformations by using catalysts derived from axially chiral binaphthyls: Bronsted acids (different from BINOL-phosphates), Lewis acids, and hydrogen-bond donors. Results published after 2004 through 2010 are presented.

引用

页码：2209 / 2222

页数：14

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