A mimic molecule of blue copper protein active site [(-)-sparteine-N,N'](maleonitriledithiolato-S,S')copper(II)

被引：41

作者：

Kim, YJ

Kim, SO

Kim, YI

Choi, SN ^{[1
]}

机构：

[1] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea

[2] Pusan Natl Univ, Dept Chem Educ, Pusan 609735, South Korea

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 17期

关键词：

D O I：

10.1021/ic001396i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new class of mimic model compounds for the type I copper site has been prepared by introducing the maleotritile-dithiolate, C4N2S22-, into the copper(II) sparteine moiety. The copper atom in the title compound adopts a distorted tetrahedral geometry with a dihedral angle of 68.0 degrees between the CuN2 and the CuS2 planes. The spectroscopic and redox properties of the compound offer a simulation of the copper donor set found in the blue copper protein. [GRAPHICS]

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页码：4481 / +

页数：5

相关论文

共 38 条

[1] Structure and function of copper-containing proteins [J].

Adman, Elinor T. .

CURRENT OPINION IN STRUCTURAL BIOLOGY, 1991, 1 (06) :895-904

[2]

ADMAN ET, 1991, ADV PROTEIN CHEM, V42, P145

[3]

ADMAN ET, 1985, TOPICS MOL STRUCTURA, V1, P1

[4] COMPLETION AND REFINEMENT OF CRYSTAL-STRUCTURES WITH SIR92 [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, C ;

GUAGLIARDI, A .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 (pt 3) :343-350

[5] BIOLOGICAL ANALOGS - PLANAR QUADRIDENTATE LIGAND WITH AN AXIAL THIOETHER TAIL [J].

AMUNDSEN, AR ;

WHELAN, J ;

BOSNICH, B .

INORGANIC CHEMISTRY, 1979, 18 (01) :206-208

[6] SYNTHESIS, STRUCTURES, AND ELECTROCHEMISTRY OF COPPER(II)-MERCAPTIDE COMPLEXES [J].

ANDERSON, OP ;

PERKINS, CM ;

BRITO, KK .

INORGANIC CHEMISTRY, 1983, 22 (09) :1267-1273

[7]

Beurskens P. T., 1994, DIRDIF 94 PROGRAM SY

[8] METAL-COMPLEXES OF 3 SPARTEINE DIASTEREOISOMERS - PROPERTIES AND REACTIVITIES OF COPPER(II) DERIVATIVES [J].

BOSCHMANN, E ;

WEINSTOCK, LM ;

CARMACK, M .

INORGANIC CHEMISTRY, 1974, 13 (06) :1297-1300

[9] HYDROLYSIS KINETICS OF (-)-SPARTEINE-COPPER(II) HALIDES .3. [J].

CADY, WA ;

BOSCHMANN, E ;

CHOI, RS ;

HEIDELMAN, JF ;

SMITH, SL .

INORGANIC CHEMISTRY, 1977, 16 (08) :1958-1961

[10] CRYSTAL-STRUCTURES OF THIOCYANATE POLYAMINE COPPER(II) COMPLEXES .4. DI-MU-THIOCYANATO-BIS[DI-(2-AMINOETHYL)AMINE]DICOPPER(II) DIPERCHLORATE [J].

CANNAS, M ;

CARTA, G ;

MARONGIU, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (06) :556-558

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