Gel synthesis by transesterification of glycol-modified poly(N-isopropylacrylamide) with O,O-diethyl dithiophosphate

被引：2

作者：

Bromberg, L ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1996年 / 17卷 / 07期

关键词：

D O I：

10.1002/marc.1996.030170707

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Synthesis of poly(N-isopropylacrylamide-co-2-hydroxyethyl methacrylate-co-ethylene glycol dimethacrylate) gels containing pendant mercapto groups via transesterification of 2-hydroxyethyl methacrylate moieties with O,O-diethyl dithiophosphate is described and the gel structure elucidated by H-1 and P-31 NMR and elemental analysis. The gels respond to changes in their liquid environment.

引用

页码：481 / 486

页数：6

共 19 条

[1]

Alimarin I.P., 1989, Russ. Chem. Rev., V58, P863

[2] DIALKYLDITHIOPHOSPHATE SUBSTITUTED ON POLY(VINYLCHLORIDE) - SYNTHESIS AND PERFORMANCE [J].