Phase diagram of nanocarbon

被引:19
作者
Danilenko, VV [1 ]
机构
[1] ALIT, UA-03067 Kiev, Ukraine
关键词
nanocarbon; phase diagram; nanodiamond; thermodynamic calculations;
D O I
10.1007/s10573-005-0056-5
中图分类号
O414.1 [热力学];
学科分类号
摘要
In the phase diagram of carbon, the positions of the melting and thermodynamic-equilibrium curves of detonation nanodiamonds or ultrafine diamonds are found as functions of diamond particle size. The position of the set of triple points located in the ranges of pressure 13.5-16.5 GPa and temperature 2210-4470 K and determining the region of the liquid state of nanocarbon is determined. In the phase diagram of nanocarbon, the diamond region is divided into three parts according to the type of nanoparticles: nanodiamond, liquid nanocarbon (nanodrops), and amorphous nanocarbon.
引用
收藏
页码:460 / 466
页数:7
相关论文
共 27 条
[1]   Diamond-graphite phase transition in ultradisperse-diamond clusters [J].
Aleksenskii, AE ;
Baidakova, MV ;
Vul, AY ;
Davydov, VY ;
Pevtsova, YA .
PHYSICS OF THE SOLID STATE, 1997, 39 (06) :1007-1015
[2]  
ALEKSENSKII AE, 1999, FIZ TVERD TELA, V41, P740
[3]   Thermodynamic stability of ultradispersed diamond phase [J].
Anisichkin, V.F. ;
Mal'kov, I.Yu. .
Combustion, Explosion and Shock Waves, 1989, 24 (05) :631-633
[4]  
[Anonymous], ZH EKSP TEOR FIZ
[5]   NANOMETRE-SIZED DIAMONDS ARE MORE STABLE THAN GRAPHITE [J].
BADZIAG, P ;
VERWOERD, WS ;
ELLIS, WP ;
GREINER, NR .
NATURE, 1990, 343 (6255) :244-245
[6]   Thermodynamics of graphite to diamond transformation [J].
Danilenko, V.V. .
Combustion, Explosion and Shock Waves, 1989, 24 (05) :633-637
[7]  
DANILENKO VV, 2003, SYNTHESIS SINTERING
[8]  
FEDOSEEV DF, 1981, DIAMOND HDB
[9]  
GUBIN SA, 1990, KHIM FIZ, V9, P401
[10]  
GUBIN SA, 1988, 4 ALL UN C DET, V1, P13