A selective instant synthesis of a coordination network and its ab initio powder structure determination

被引：59

作者：

Kawano, Masaki ^{[1
]}

Haneda, Tsuyoshi ^{[1
]}

Hashizume, Daisuke ^{[2
]}

Izumi, Fujio ^{[3
]}

Fujita, Makoto ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] RIKEN, Mol Characterizat Team, Wako, Saitama 3510198, Japan

[3] Natl Inst Mat Res, Quantum Beam Ctr, Tsukuba, Ibaraki 3050044, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 07期

关键词：

host-guest systems; kinetic control; materials science; porous structures; X-ray diffraction;

D O I：

10.1002/anie.200704809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Fast powders and slow crystals: A uniform powder sample of a flexible porous coordination network is prepared in high yield by kinetically controlled synthesis and its crystal structure solved by synchrotron ab initio powder X-ray diffraction (see picture). Crystals of a totally different porous network with larger channels for guest encapsulation are also obtained by thermodynamic control in a slow crystallization process. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1269 / 1271

页数：3

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