Electrolytic partial fluorination of organic compounds. Part 57: Regioselective anodic monofluorination of nitrogen-containing heterocyclic propargyl sulfides

被引：17

作者：

Riyadh, SM ^{[1
]}

Ishii, H ^{[1
]}

Fuchigami, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

TETRAHEDRON | 2001年 / 57卷 / 42期

关键词：

selective fluorination; electrochemical fluorination; alpha-fluoro heterocyclic sulfide;

D O I：

10.1016/S0040-4020(01)00866-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anodic fluorination of various nitrogen-containing heterocyclic propargyl sulfides using Et4NF . nHF (n=3,4) or Et3N . 3HF as a supporting electrolyte and fluoride ion source in dimethoxyethane provided the corresponding monofluorinated products in moderate yields. Fluorination took place selectively at the position a to the sulfur atom of the sulfides and the heterocyclic moieties were riot fluorinated at all. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：8817 / 8821

页数：5

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