Aqua(hexamethylenetetramine-κN)bis(methanol)bis(thiocyanato-κN)nickel(II)

被引：7

作者：

Bai, Yan ^{[1
]}

Shang, Wei-Li ^{[1
]}

Zhang, Fu-Lian ^{[1
]}

Pan, Xiao-Jing ^{[1
]}

Niu, Xiao-Fang ^{[1
]}

机构：

[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Henan 475004, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807046648

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Ni atom in the title complex, [Ni(SCN)2(C6H14N4)(CH4O)2(H2O)], is six-coordinate in a slightly distorted octa-hedral environment. The hexa-methyl-enetetra-mine ligand binds to the Ni atom through only one of its N atoms, trans to the coordinated water mol-ecule. The thio-cyanate and methanol ligands are also mutually trans. In the crystal structure, complex mol-ecules are linked by four different kinds of hydrogen bonds (O - H⋯S, O - H⋯N, C - H⋯N and C - H⋯O) to form a three-dimensional network structure. © International Union of Crystallography 2007.

引用

页码：M2628 / U1808

页数：10

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