Stable bis(silyl)nickel complexes with o-carboranyl unit:: a facile double silylation of alkynes and alkenes

被引：39

作者：

Kang, YJ

Lee, J

Kong, YK

Kang, SO ^{[1
]}

Ko, J

机构：

[1] Korea Univ, Dept Chem, Chungnam 339700, South Korea

[2] Kyunggi Univ, Dept Chem, Suwon 440760, South Korea

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 21期

关键词：

D O I：

10.1039/a806457a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of o-bis(dimethylsilyl)carborane with Ni(PEt3)(4) in pentane affords the reactive intermediate, [o-(SiMe2)(2)C2B10H10]Ni(PEt3)(2) 2; the facile double silylation of alkynes catalyzed by 2 is reported.

引用

页码：2343 / 2344

页数：2

共 9 条

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