Catalytic oxidation of tetrahydrofuran in the presence of transition metal complexes under aerobic conditions

被引：16

作者：

Shi, M ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1998年 / 09期

关键词：

D O I：

10.1039/a803377c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon stirring a THF solution of a transition metal under an aerobic atmosphere, gamma-butyrolactone and a small amount of lactol and 4-hydroxybutyraldehyde are formed; the turnover number of this catalytic oxidation process can reach 150 when IrCl(CO)(PPh3)(2) is used.

引用

页码：592 / 593

页数：2

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