Synthesis of a pyridinophane with endo-annular donor sites

被引：14

作者：

Campbell, K

Tiemstra, NM

Prepas-Strobeck, NS

McDonald, R

Ferguson, MJ

Tykwinski, RR ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

[2] Univ Alberta, Dept Chem, Xray Crystallog Lab, Edmonton, AB T6G 2M7, Canada

来源：

SYNLETT | 2004年 / 01期

关键词：

alkynes; cross-conjugation; cross-coupling; homocoupling; macrocycles; pyridines;

D O I：

10.1055/s-2003-43346

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Our synthetic efforts toward the realization of cross-conjugated macrocycles containing 2,6-diethynylpyridine sub-units are described. Macrocycle 4b was efficiently constructed from easily accessible building blocks using a series of palladium-catalyzed cross-coupling and copper-catalyzed homocoupling reactions. The synthesis, characterization and solid state characteristics of this macrocycle, as well as its precursors are provided in the discussion that follows.

引用

页码：182 / 186

页数：5

共 22 条

[1] Synthesis and fluorescence ion-sensory properties of the first dehydropyridoannulene-type cyclophane with enforced exotopic metal ion binding sites [J].