Theoretical and synthetic studies on [Zn2(η5-C5Me5)2]:: Analysis of the Zn-Zn bonding interaction

被引：118

作者：

del Río, D

Galindo, A

Resa, I

Carmona, E

机构：

[1] Univ Seville, Dept Quim Inorgan, Seville 41071, Spain

[2] CSIC, Inst Invest Quim, Seville 41092, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 08期

关键词：

bond energy; cyclopentadienyl ligands; density functional calculations; metallocenes zinc;

D O I：

10.1002/anie.200462175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

More than 1 g of the dizinc compound [Zn2(η5- C5Me5)2] can be readily obtained in a single preparation. Density functional calculations reveal that the Zn-Zn bond is relatively strong and derives mainly from interaction between the Zn 4 s orbitals (see picture). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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页码：1244 / 1247

页数：4

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