Synthesis of the A/E/F sections of conaconitine, napelline and related diterpenoid alkaloids of the aconitine group

被引：25

作者：

Baillie, LC

Batsanov, A

Bearder, JR

Whiting, DA

机构：

[1] Univ Nottingham, Dept Chem, Nottingham NG7 2RD, England

[2] Shell Res & Technol Ctr, Chester CH1 3SH, Cheshire, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 20期

关键词：

D O I：

10.1039/a804664f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The tricyclic amines (+/-)-2; R = H and R = Me with five stereogenic centres, representing the A/E/F ring system of the title alkaloids, have been synthesised from penta-1,4-dien-3-ol in eight (overall yield 20%) and nine steps (overall yield 16%) respectively.

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页码：3471 / 3478

页数：8

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