Metal-specific allosteric activation and deactivation of a diamine

被引：7

作者：

Clayton, Hayley J. ^{[1
]}

Harding, Lindsay P. ^{[1
]}

Irvine, John P.

Jeffery, John C. ^{[2
]}

Riis-Johannessen, T. ^{[2
]}

Laws, Andrew P. ^{[1
]}

Rice, Craig R. ^{[1
]}

Whitehead, Martina ^{[1
]}

机构：

[1] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 01期

关键词：

D O I：

10.1039/b714256k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of a potentially tetradentate bis(pyridyl-thiazole) ligand with acetone is allosterically activated upon complexation with Cd(II) but deactivated by reaction with Cu(I), demonstrating metal-specific allosteric controlled reactivity.

引用

页码：108 / 110

页数：3

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