Is samarium diiodide an inner- or outer-sphere electron donating agent?

被引：105

作者：

Enemaerke, RJ ^{[1
]}

Daasbjerg, K ^{[1
]}

Skrydstrup, T ^{[1
]}

机构：

[1] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 04期

关键词：

D O I：

10.1039/a809277j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From the measured value of E degrees (SmI2+-SmI2) in THF and using free energy plots, the electron transfer between samarium diiodide and acetophenone was shown to be clearly of inner-sphere nature; on the other hand, with benzyl bromide it is closer to an outer-sphere process.

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收藏

页码：343 / 344

页数：2

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