Synthesis and Characterization of Thiophene-Containing Naphthalene Diimide n-Type Copolymers for OFET Applications

被引：164

作者：

Durban, Matthew M. ^{[2
]}

Kazarinoff, Peter D. ^{[1
]}

Luscombe, Christine K. ^{[1
]}

机构：

[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA

[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA

来源：

MACROMOLECULES | 2010年 / 43卷 / 15期

基金：

美国国家科学基金会;

关键词：

FIELD-EFFECT TRANSISTORS; ORGANIC SEMICONDUCTORS; ELECTRON-TRANSPORT; SOLAR-CELLS; POLYMERS; DERIVATIVES; MOBILITY; DESIGN; PERFORMANCE; DEPOSITION;

D O I：

10.1021/ma100997g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Naphthalene diimide (NDI) copolymers are attractive n-type materials for use in organic electronic devices. Four highly soluble NDI polymers are presented-each differing only in the thiophene content comprising the material. Electron mobilities as high as 0.076 cm(2) V-1 s(-1) for the novel material PNDI-3Th are reported. Polymer crystallinity and general macromolecular order are shown to effectively improve by increasing the number of thiophene units within the polymer backbone. The structure-property relationship of NDI-thiophene copolymers is presented and discussed as it pertains to organic field effect transistor (OFET) performance.

引用

页码：6348 / 6352

页数：5

共 31 条

[1] Organic semiconductors for solution-processable field-effect transistors (OFETs) [J].

Allard, Sybille ;

Forster, Michael ;

Souharce, Benjamin ;

Thiem, Heiko ;

Scherf, Ullrich .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (22) :4070-4098

[2]

Asawapirom U, 2002, SYNTHESIS-STUTTGART, P1136

[3] Living anionic polymerization of 2-vinyidibenzothiophene:: Homopolymer and block copolymers with styrene [J].

Avila-Ortega, A. ;

Vazquez-Torres, H. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (10) :1993-2003

[4] Toward a rational design of poly(2,7-carbazole) derivatives for solar cells [J].

Blouin, Nicolas ;

Michaud, Alexandre ;

Gendron, David ;

Wakim, Salem ;

Blair, Emily ;

Neagu-Plesu, Rodica ;

Belletete, Michel ;

Durocher, Gilles ;

Tao, Ye ;

Leclerc, Mario .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (02) :732-742

[5] Self-assembly, molecular packing, and electron transport in n-type polymer semiconductor nanobelts [J].

Briseno, Alejandro L. ;

Mannsfeld, Stefan C. B. ;

Shamberger, Patrick J. ;

Ohuchi, Fumio S. ;

Bao, Zhenan ;

Jenekhe, Samson A. ;

Xia, Younan .

CHEMISTRY OF MATERIALS, 2008, 20 (14) :4712-4719

[6] Linearly extended hybrid tetrathiafulvalene analogues with bridged dithienylethylene pi-conjugating spacers [J].

Brisset, H ;

LeMoustarder, S ;

Blanchard, P ;

Illien, B ;

Riou, A ;

Orduna, J ;

Garin, J ;

Roncali, J .

JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (10) :2027-2032

[7]

BRISSET H, 1994, CHEM COMMUN, V1, P1765

[8] Naphthalenedicarboximide- vs Perylenedicarboximide-Based Copolymers. Synthesis and Semiconducting Properties in Bottom-Gate N-Channel Organic Transistors [J].

Chen, Zhihua ;

Zheng, Yan ;

Yan, He ;

Facchetti, Antonio .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) :8-+

[9] Ambipolar transport in organic conjugated material [J].

Cornil, Jerome ;

Bredas, Jean-Luc ;

Zaumseil, Jana ;

Sirringhaus, Henning .

ADVANCED MATERIALS, 2007, 19 (14) :1791-1799

[10] Large-scale complementary integrated circuits based on organic transistors [J].

Crone, B ;

Dodabalapur, A ;

Lin, YY ;

Filas, RW ;

Bao, Z ;

LaDuca, A ;

Sarpeshkar, R ;

Katz, HE ;

Li, W .

NATURE, 2000, 403 (6769) :521-523

← 1 2 3 4 →