Investigation of the Payne effect and its temperature dependence on silica-filled polydimethylsiloxane networks.: Part II:: Test of quantitative models

被引:24
作者
Clément, F [1 ]
Bokobza, L [1 ]
Monnerie, L [1 ]
机构
[1] ESPCI, Lab PCSM, UMR 7615, F-75231 Paris, France
来源
RUBBER CHEMISTRY AND TECHNOLOGY | 2005年 / 78卷 / 02期
关键词
D O I
10.5254/1.3547880
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The results obtained in Part 1, on Polydimethylsiloxane (PDMS) networks filled with treated Aerosil A300 silica at variable temperature and various loadings, have been used to test the quantitative models of the Payne effect proposed by Kraus, Huber-Vilgis, and Maier-Goritz. Each model is able to account only for a part of the experimental results: Kraus and Maier-Vilgis for the variation, of the Payne effect with filler Volume fraction, Maier-Goritz for the influence of temperature on the Payne effect. But neither of these quantitative models is able to fit the whole set of experimental results on G' and G'' with a unique set of parameters.
引用
收藏
页码:232 / 244
页数:13
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