Synthesis and X-ray structures of silver and gold guanidinate-like complexes.: A Au(II) complex with a 2.47 Å Au-Au distance

被引：65

作者：

Irwin, MD ^{[1
]}

Abdou, HE ^{[1
]}

Mohamed, AA ^{[1
]}

Fackler, JP ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, Mol Struct & Bonding Lab, College Stn, TX 77843 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 23期

关键词：

D O I：

10.1039/b309724m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structures of the tetranuclear silver( I), [ Ag-4( hpp) (4)], and the dinuclear gold( II), [ Au-2( hpp) Cl-2(2)], ( hpp = 1,3,4,6,7,8- hexahydro- pyrimido[ 1,2- a] pyrimidinate) guanidinate-like bases are reported and show a silver - silver distance of 2.8614( 6) Angstrom and a gold - gold distance of 2.4752( 9) Angstrom, the shortest Au - Au bond heretofore reported.

引用

页码：2882 / 2883

页数：2

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