Electronic influence of ligand substituents on the rate of polymerization of ε-caprolactone by single-site aluminium alkoxide catalysts

被引:152
作者
Alcazar-Roman, LM [1 ]
O'Keefe, BJ [1 ]
Hillmyer, MA [1 ]
Tolman, WB [1 ]
机构
[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
关键词
D O I
10.1039/b303760f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of novel five-coordinate aluminium mono alkoxide complexes supported by (R1,R2)BPBA (bis-3-R-1-5-R-2-phenoxymethyl-bisamine) ligands were synthesized to probe the effect of electronic variation in the supporting ligand on the rate of epsilon-caprolactone polymerization. Substitution on the aromatic position para to the phenoxide donor oxygen by tert-butyl, methoxy and bromo substituents furnished aluminium complexes that catalyzed the polymerization of epsilon-caprolactone at different rates. We propose that a subtle interplay between complex Lewis acidity and alkoxide nucleophilicity determines the overall rate of polymerization in these systems.
引用
收藏
页码:3082 / 3087
页数:6
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