Microporous rhodium(II) 4,4',4",4'"-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakisbenzoate.: Synthesis, nitrogen adsorption properties, and catalytic performance for hydrogenation of olefin

被引：28

作者：

Sato, T

Mori, W

Kato, CN

Ohmura, T

Sato, T

Yokoyama, K

Takamizawa, S

Naito, S

机构：

[1] Kanagawa Univ, Fac Sci, Dept Chem, Hiratsuka, Kanagawa 2591293, Japan

[2] Yokohama City Univ, Fac Sci, Dept Syst Funct, Kanazawa Ku, Yokohama, Kanagawa 2360027, Japan

[3] Kanagawa Univ, Fac Engn, Dept Appl Chem, Yokohama, Kanagawa 2218686, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 09期

关键词：

D O I：

10.1246/cl.2003.854

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel microporous rhodium(H) coordination polymer, [Rh-2(H2TCPP)] (1) (H2TCPP = 4,4',4",4"'-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis benzoic acid) was synthesized. The complex I showed high porosity of the micropores of 7.3 Angstrom. The amount of nitrogen adsorbed by 1 was 2.87 mole per mole of Rh, which is about three times that of rhodium(II) fumarate and rhodium(II) terephthalate. Complex I also showed high turnover frequencies for the hydrogenation of ethylene and propene at ca. 200 K.

引用

页码：854 / 855

页数：2

共 21 条

[1] Quantitative formation of coordination nanotubes templated by rodlike guests [J].