Constructing a stable carbene with a novel topology and electronic framework

被引：203

作者：

Bazinet, P

Yap, GPA

Richeson, DS ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

[2] Univ Ottawa, Ctr Catalysis Res & Innovat, Ottawa, ON K1N 6N5, Canada

[3] Univ Delaware, Dept Biochem & Chem, Newark, DE 19716 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 44期

关键词：

D O I：

10.1021/ja0372661

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The perimidine skeleton provides a framework for the isolation of a novel, stable carbene possessing a unique molecular architecture and electronic structure. The remarkable steric environment and exceptional electron-donating ability for the carbene-carbon are revealed through structural and spectroscopic characterization of the parent carbene and two sterically encumbered rhodium-carbene complexes, L2RhCl{C[NCH(CH3)2]2(C10H6)} (5 L2 = COD; 6 L = CO). Copyright © 2003 American Chemical Society.

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页码：13314 / 13315

页数：2

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