Concentration-dependent NMR and conductivity studies of (PEG)(x)NH4ClO4

被引：16

作者：

Binesh, N ^{[1
]}

Bhat, SV ^{[1
]}

机构：

[1] INDIAN INST SCI,DEPT PHYS,BANGALORE 560012,KARNATAKA,INDIA

来源：

SOLID STATE IONICS | 1996年 / 92卷 / 3-4期

关键词：

polymer electrolyte; protonic conductor; ionic conductivity; NMR;

D O I：

10.1016/S0167-2738(96)00482-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Films of (PEG)(x)NH4ClO4 (x = 5 to 1000) were prepared and characterized. The physical properties are observed to be a sensitive function of concentration. Hygroscopicity increases as salt content increases. Conductivity peaks (sigma = 2.7 x 10(-6) S/cm) at x = 46. The H-1 NMR line width has a minimum at x = 46, while that of Cl-35 monotonically increases with salt concentration, indicating that the complex is essentially a protonic conductor.

引用

页码：261 / 264

页数：4

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